Month: October 2016

Bond Order is and it is Paramagnetic. There are two MO diagrams you need to memorize for diatoms ( N, O Ne etc). One is for the elements up to Nitrogen. This is the reasoning for the rearrangement from a more familiar diagram.

Here is the full molecular orbital diagram for N 2. Now we add the electrons, from each nitrogen atom. Note that the bottom sigma symmetry orbital is strongly bonding, the top one is strongly antibonding, and the in the middle are only weakly bonding and antibonding, respectively. Nmolecular orbital energy level diagram picture, is usually depicted by a diatomic molecules.

How to do orbital diagrams? What is molecular orbital model? The short answer is: we could not tell it using the primitive molecular orbital theory introduced in the general chemistry courses. If we build the MO diagram for N _ , it looks like this: First though, notice that the p orbitals are supposed to be degenerate. Anyways, for the electron configurations, you would use a notation like the above.

MO diagram is different for molecules with or less electrons than the one used for molecules with or more electrons. For Nthe orbitals in increasing energy are: σ1sσ∗1sσ2sσ∗2sπ2px,π2pyσ2pzπ∗2px,π∗2pyσ∗2pz because it has electrons. Jmol models of calculated wavefunctions. To view a model, click on a molecular orbital in the energy level correlation diagram shown Mouse Control of Models.

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How to obtain a no-fee passport? How much does a new passport cost? Overseas processing surcharge. Child passport for 0-year olds, 5-year validity. Total cost for 0-year olds.

Senior passport (years or older), 5-year validity. Step 5: Get passport photos. Make sure they comply with our photo guidelines. In some locations, you may need to book an appointment.

We’ll use information in the passport database to verify your details. Both fees are collected and retained by law even if a passport is not issued. Service Commitment Our expedited service commitment is to process your passport application within business days from the date we receive your application at a passport agency or center (or from the date you request expedited service).

Fees are subject to annual indexation. No GST is payable on passport fees. Receiving your new passport. You should allow approximately weeks to receive your new passport. Australian dollar amounts are shown as a guide only.

It will be sent to you by Royal Mail Special Delivery (see Additional fees and services). (more…)

What is professional indemnity insurance? Why is indemnity insurance important? Does qgif cover indemnity? Professional Indemnity (PI) insurance provides financial protection and may cover the costs if a contractor has caused building errors or omissions.

Getting PI insurance is a requirement for some licensees and is a matter of simply contacting an insurance provider. You can view a list of licence classes that require PI in the MFR Regulation. Once you become license you need to make sure that your insurance remains active. This means QGIF will cover the Agency for an incident which occurs during the period when the policy was in force, regardless of when a claim is made or reported to QGIF.

Specialist services needing protection can be wide and varied. Insurance for Accountants. What does professional indemnity insurance cover ? Better wages and conditions.

The QNMU is the organisation that negotiates at the bargaining table on behalf of Queensland’s nurses and midwives. Appropriately qualified and skilled personnel will support any workplace-related matter involving compliance to legislation such as entitlements, bullying and harassment, workplace health and safety or Workcover issues in accordance with By-Laws. The Nursing and Midwifery Board of Australia (NMBA) undertakes functions as set by the Health Practitioner Regulation National Law, as in force in each state and territory (the National Law). (more…)

What is the meaning of deed of variation? Why do I need a variation deed? Can I put a deed of variation in place after probate? A beneficiary who gives up their entitlement makes a lifetime disposition, which may be a gift (a voluntary disposition) or may be for consideration. Deed of variation In-house.

Precedent , see Practice Notes:. Use a deed of variation of a will to change the entitlements of beneficiaries of a will. It can apply to one or more beneficiaries.

You can use it to change the will of a person after their death. Use this deed where a person has died and has left a will. This standard document is for use where a landlord and a tenant agree to vary the terms of their lease. It provides a framework that can be used by the parties to document the particular changes that they have agreed.

Variation of the Lease. This can be the date the deed of variation for a leas is dated or a future date. Avoid stating a past date, as this can have unintended consequences. The parties to this variation intend that the provisions of section. NOW THIS DEED WITNESSES as follows: In pursuance of the said agreement and in consideration of the.

WHY YOU NEED A VARIATION DEED TO AMEND AN INITIAL AGREEMENT. The deed allows the beneficiary to redirect their entitlement to another person, without suffering any tax consequences. (more…)

As we know, a month business visa is US$and it is easily extendable once you arrive in the country! Do I need to pay the postal fee to receive visa by mail? It seems US$ is the total fee you have to pay including the postal fee. However, we suggest that you contact the embassy directly for more information.

On June authorities released a fee schedule for these testing and treatment services. Travelers should be prepared to see this deposit applied to a minimum of $ 1for mandatory COVID-testing, approximately $2more to support quarantine in the event.

The application fee for the most common nonimmigrant visa types is US$ 160. This includes tourist, business, student, and exchange visas. Most petition-based visas, such as work and religious visas, are US$190.

K visas cost US$2and the fee amount for E visas is US$2The tables below have a more comprehensive list of visa types and fee amounts. Overstay fee is US$per day. Sometimes, in some border checkpoints, you may be asked to pay a certain additional amount for processing fee. There is nothing to pay more than that.

Skip long queues and boring procedures to get a Visa.

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What to write in a landlord reference letter? Step Begin the letter with a formal greeting and state the purpose in the opening line. How to request a character reference letter? Sometimes, landlords also ask for income verification and salary statement as proof. This ensures the property owner that the person he may be letting out his property too is a reliable one.

Think about the aspects of your friend that are strong character traits , and jot them down on a scratch pad. Introduce the purpose of the letter with a line about the purpose of your letter and how you know the person who. Rental Reference Letter From Friend This is simply a kind of reference written by a close friend to vouch for a prospective tenant ’s agreeable qualities. You are required to write a persuasive letter to make sure your friend occupies the apartment. You must use good and polite words in the letter.

A character reference letter is also known as a personal reference letter. It is a document written by an individual who knows the job candidate at a personal level. It can be written by a friend , relative or neighbor. The primary purpose of this document is to attest to the character and abilities of the candidate. As the name indicates it highlights the character of that person and it is important that the person writing this letter should be honest in their feelings and only then should agree to write about it.

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Angle of Depression Examples. If the vehicle is away from the building at a distance of 1meters , find the height of the tower. Solution: In the above figure, R is a vehicle.

PQ is the height of the tower. RQ is the distance between the tower and the vehicle. PS is the line of sight.

So, angle of depression from point B is 45°. BX is the horizontal. Now, we need to find the distance of point A from the building. Now, lines BX and AC are parallel, and AB is the transversal. So, Alternate angles are equal.

The opposite side in this case is usually the height of the observer or height in terms of location, for. Tangent is the main ratio that is used to determine the angle of depression. It may be found by using this equation tan y is equal to opposite divided by the adjacent side.

Problem : From the top of a rock √ m high, the angle of depression of a car on the ground is observed to be 30°. Find the distance of the car from the rock. For example, if you were standing on top of a hill or a building, looking down at an object, you could measure the angle of depression. The angle of depression is the angle between the horizontal line of sight and the line of sight down to an object.

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Magical DIY Christmas Snow Globes – Christmas Celebration. How to make a snow globe wreath? Fill a Mason jar with pickling salt and place animal figurines inside. What is a sleigh ride snow globe?

Make the scene even more realistic by adding pebbles and bottle brush trees.

Get the tutorial at Classic Play. Courtesy of Mason Jar Crafts Love. Just look at the beautiful scene this car is creating? Doesn’t it want to make you jump right into the.

Fishbowl Snow Globe. Did you know, you could even use a fishbowl to make a Christmas snow globe ? Print family photos and laminate them so they stay safely sealed for a personalized craft. These festive DIY Christmas snow globes are a fun way to decorate for the holiday season.

And they’re also a fun craft to make with during the Christmas season! While traditional snow globes use liquid inside to help the “ snow ” float, making your own liquid-filled snow globe can get pretty messy. These snow globes with make your home a winter wonderland.

This collection of DIY snow globes with tutorials is sure to WOW you. (more…)

For hundreds of years hand-written invoicing has been the standard for most businesses, at least until electronically generated invoices became standard practice for most companies. In fact, hand-written invoices are still common in a variety of industries. An invoice is not a legal document on its own. While invoicing is an important accounting practice for businesses, invoices do not serve as a legally binding agreement between the business and its client. That’s because an invoice leaves too much room for manipulation to serve as a legal document.

My local distributor gives hand written invoices to all walk in customers so the bogus claim of “FAKE” on a return and amazons recent crack down I seem a bit stuck.

I sent them in two recent invoices for a few thousand worth of product but it got denied to to being hand written. Or instead of a statement in sentences, you could just write INVOICE at the very top, then your name and address, then something like writing assignment (then leave a couple inch space) then $100. Packages always have invoices, etc. Technically, if you write a letter or note, you should add postage for it. As far as I know, they are not allowed to with hold your file.

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Belgium has seen an increase in the size of its migrant population over the last two decades. Around 150people move to the country each year and approximately of Belgian residents were foreign-born. As it is part of the Schengen Area, Belgium allows many EU residents passport-free travel into the country. You must open a company which can take several months and must have capital of EUR 1600.

One is eligible to apply for citizenship after just years legal continious residence.

Yet over the last three decades Belgium has become a permanent country of settlement for many different types of migrants. Our updated Belgium profile delves into modern migration flows and policies in Belgium which are inching away from a piecemeal approach towards a well. Upon arrival in Belgium , you have eight working days to contact the municipal authorities of your place of residence in order to obtain an Electronic Foreigner Card type A. Duration of validity of permit: The period of validity of the residence permit (Electronic Foreigner Card type A) is equal to that of the work permit plus one month. The Moroccans are the third-largest group, and the largest Muslim ethnic group, numbering 22000.

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